910298-05-4Relevant academic research and scientific papers
A Convergent Radical Based Route to Trifluoromethyl Ketones and to α,β-Unsaturated Trifluoromethyl Ketones
Anthore, Lucile,Zard, Samir Z.
supporting information, p. 3058 - 3061 (2015/06/30)
A convergent synthesis of trifluoromethyl ketones and α,β-unsaturated trifluoromethyl ketones is described, starting with aliphatic iodides and dithiocarbonates (xanthates) and exploiting both the α- and β-fragmentations of a sulfonyl radical. The transfo
Radicals from aldehydes: A convergent access to dienes and δ-lactones
Bagal, Sharanjeet K.,Tournier, Lucie,Zard, Samir Z.
, p. 1485 - 1490 (2007/10/03)
A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes
