51632-22-5Relevant academic research and scientific papers
Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
Jiao, Zhiwei,Chee, Kwok Wei,Zhou, Jianrong Steve
supporting information, p. 16240 - 16243 (2016/12/27)
Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.
