51643-91-5Relevant academic research and scientific papers
Novel, Metal-Catalyzed Carbonylation of Acyclic Organic Compounds. The Regiospecific Carbonylation of N,S-Acetals
Khumtaveeporn, Kanjai,Alper, Howard
, p. 1414 - 1417 (1994)
The rhodium(I) complex, 2, catalyzes the regiospecific carbonylation of N,S-acetals of structural type PhCH2SCH2NR1R2 to form PhCH2COSCH2NR1R2 in 68-92percent isolated yields.Exclusive insertion of carbon monoxide occurs into the other sulfur-carbon bond of RSCH(Ph)NR3R4 (R = PhCH2, n-C11H23) affording RSCOCH(Ph)NR3R4 in 46-83percent yield.
