Novel, Metal-Catalyzed Carbonylation of Acyclic Organic Compounds. The Regiospecific Carbonylation of N,S-Acetals

DOI: 10.1021/jo00085a034

Source and publish data:

Journal of Organic Chemistry p. 1414 - 1417 (1994)

Update date:2022-08-02

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Authors:

Khumtaveeporn, Kanjai

Alper, Howard

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Article abstract of DOI:10.1021/jo00085a034

The rhodium(I) complex, 2, catalyzes the regiospecific carbonylation of N,S-acetals of structural type PhCH2SCH2NR1R2 to form PhCH2COSCH2NR1R2 in 68-92percent isolated yields.Exclusive insertion of carbon monoxide occurs into the other sulfur-carbon bond of RSCH(Ph)NR3R4 (R = PhCH2, n-C11H23) affording RSCOCH(Ph)NR3R4 in 46-83percent yield.

Full text of DOI:10.1021/jo00085a034

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