51652-45-0Relevant academic research and scientific papers
Chemistry of natural compounds and bioorganic chemistry a convergent synthesis of octadeca-2E,13Z-dienyl acetate, a pheromone component of Synanthedon tipuliformis C
Ishmuratov,Yakovleva,Kharisov,Kunafina,Gorobets,Kuchin,Tolstikov
, p. 1465 - 1467 (2007/10/03)
A convergent synthesis of octadeca-2E,13Z-dienyl acetate, a pheromone component of Synanthedon tipuliformis C., has been developed. The synthesis is based on cross-coupling of 8-iodooct-2E-en-1-ol THP ether with dec-57-enyl bromide catalyzed by CuBr.
A Tandem Synthesis of (+/-)-Euphococcinine and (+/-)-Adaline
Davison, Edwin C.,Holmes, Andrew B.,Forbes, Ian T.
, p. 9047 - 9050 (2007/10/02)
Intramolecular hydroxylamine-alkyne cyclisation of the hydroxylamines 8 and 9 afforded six-membered cyclic nitrones which without isolation underwent a tandem intramolecular dipolar cycloaddition to produce the tricyclic isoxazolidines 6 and 7 respectively.These were converted in two steps into the ladybird defence alkaloids (+/-)-euphococcinine 4 and (+/-)-adaline 5.
SYNTHESIS OF HIGHER ACETYLENIC ALCOHOLS
Kovalev, B. G.,Matveeva, E. D.,Stan, V. V.,Vovk, G. A.,Yudin, L. G.,Kost, A. N.
, p. 1728 - 1733 (2007/10/02)
The alkylation of 1-alkynes in various solvents was investigated, and the optimum conditions for the production of acetylenic alcohols were obtained.
