624-20-4Relevant articles and documents
Facile one-pot synthesis of α-bromoketones from olefins using bromide/bromate couple as a nonhazardous brominating agent
Patil, Rajendra D.,Joshi, Girdhar,Adimurthy, Subbarayappa,Ranu, Brindaban C.
experimental part, p. 2529 - 2532 (2009/09/06)
A new method for the preparation of α-bromoketones from olefins using bromide/bromate couple as a nonhazardous brominating agent has been developed. Several α-bromoketones were successfully prepared from a variety of olefins by this method. This procedure is an alternative to conventional molecular bromine.
ELECTRON TRANSFER IN REACTIONS OF tert-PERFLUOROALKYL BROMIDES WITH ALKENES AND NUCLEOPHILES
Rozhkov, I. N.,Chaplina, I. V.
, p. 2451 - 2456 (2007/10/02)
Tertiary perfluoroalkyl bromides (RFBr) in nonpolar solvents under mild conditions can be added to the multiple bond of terminal alkenes, alkynes, and butadiene.Slow addition to alkenes at 20 deg C is accelerated in proton-donating solvents and is catalyzed by readily oxidizable nucleophiles.Bromination of the multiple bond and formation of RFBr reduction products suggests a radical-chain mechanism initiated by electron transfer to the RFBr molecule.