51673-93-9Relevant articles and documents
Preparation method of substituted piperidine derivative
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Paragraph 0020; 0021; 0022, (2017/12/27)
The invention discloses a preparation method of a substituted piperidine derivative 4(tert-butyl(2-(aminomethyl)-6-methylphenoxy)methyl)piperidine-1-carboxylate. The preparation method comprises the steps of carrying out oximation, elimination, etherifica
Cytokinin receptor antagonists derived from 6-benzylaminopurine
Nisler, Jaroslav,Zatloukal, Marek,Popa, Igor,Dole?al, Karel,Strnad, Miroslav,Spíchal, Luká?
body text, p. 823 - 830 (2010/07/04)
Recently we reported 6-(2-hydroxy-3-methylbenzylamino)purine (PI-55) as the first molecule to antagonize cytokinin activity at the receptor level. Here we report the synthesis and in vitro biological testing of eleven BAP derivatives substituted in the be
Magnesium-mediated ortho-Specific Formylation and Formaldoximation of Phenols
Aldred, Robert,Johnston, Robert,Levin, Daniel,Neilan, James
, p. 1823 - 1832 (2007/10/02)
Deprotonation of phenols using magnesium methoxide, followed by distillative removal of free methanol and addition of paraformaldehyde results in ortho-specific magnesium mediated formylation to give the corresponding salicyladehyde magnesium salts, from which the salicylaldehydes can be isolated by acidic work-up.Addition of aq. hydroxylamine sulfate to the salicylaldehyde magnesium salt, in place of the acid work-up, gives the corresponding salicylaldoximes.
