1104058-34-5Relevant academic research and scientific papers
A general and convenient route to oxazolyl ligands
Aspinall, Helen C.,Beckingham, Oliver,Farrar, Michael D.,Greeves, Nicholas,Thomas, Christopher D.
, p. 5120 - 5123 (2011/10/19)
A diverse range of chiral and achiral oxazolyl ligands, which have many applications including catalysis and luminescent devices, are synthesized simply in three steps from readily available and inexpensive phenol and amino alcohol starting materials. The method can be applied to ligands with electron-donating/-withdrawing and sterically demanding/undemanding substituents, and can conveniently be scaled up to >25 g of product.
Lewis base assisted Bronsted base catalysis: Bidentate phosphine oxides as activators and modulators of bronsted basic lanthanum-aryloxides
Morimoto, Hiroyuki,Yoshino, Tatsuhiko,Yukawa, Takafumi,Lu, Gang,Matsunaga, Shigeki,Shibasaki, Masakatsu
supporting information; experimental part, p. 9125 - 9129 (2009/02/08)
(Chemical Equation Presented) Dynamic Duo: A Lewis basic bidentate phosphine oxide was effective for activating and modulating the properties of Bronsted basic lanthanum aryl oxides. The Lewis base 1/lanthanum aryl oxide system was suitable for anti-selective Mannich-type reactions of trichloromethyl ketones (see scheme), affording unique building blocks for azetidine-2-carboxylic acids as well as β-amino acids.
