5171-96-0Relevant articles and documents
Exploring the Influence of Phosphine Ligation on the Gold-Catalyzed Hydrohydrazination of Terminal Alkynes at Room Temperature
Rotta-Loria, Nicolas L.,Chisholm, Alicia J.,MacQueen, Preston M.,McDonald, Robert,Ferguson, Michael J.,Stradiotto, Mark
supporting information, p. 2470 - 2475 (2017/07/17)
The synthesis and/or NMR/X-ray characterization of a new series of (L)AuCl complexes is reported, featuring BippyPhos, AdJohnPhos, silyl ether based ligands including OTips-DalPhos, and PAd-DalPhos. These complexes, along with previously reported analogue
Regioselective one-step synthesis of pyrazoles from alkynes and N-tosylhydrazones: [3+2] dipolar cycloaddition/[1,5] sigmatropic rearrangement cascade
Pérez-Aguilar, M. Carmen,Valdés, Carlos
supporting information, p. 7219 - 7223 (2013/07/26)
Rearrangement under control: A wide variety of 3,4,5- and 1,3,5-trisubstituted pyrazoles can be prepared from tosylhydrazones of ketones and terminal alkynes through the title reaction sequence (see scheme; Ts=4-toluenesulfonyl). The rearrangement, and th
Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine
Kinjo, Rei,Donnadieu, Bruno,Bertrand, Guy
supporting information; experimental part, p. 5560 - 5563 (2011/07/30)
A diverse array of nitrogen-containing compounds were formed by the addition of hydrazine to alkynes, diynes, enynes, and allenes in the presence of cationic gold(I) complexes with a cyclic (alkyl)(amino)carbene ligand (see scheme; the X-ray crystal structure of the gold-hydrazine complex is shown). This hydroamination is an ideal initial step for the preparation of acyclic and heterocyclic bulk chemicals. Dipp=2,6-diisopropylphenyl. Copyright