51719-45-0Relevant articles and documents
Transition metal catalysed cross-coupling between benzylic halides and aryl nucleophiles. Synthesis of some toxicologically interesting tetrachlorobenzyltoluenes
De Lang, Robbert-Jan,Van Hooijdonk, Marcel J.C.M.,Brandsma, Lambert,Kramer, Hester,Seinen, Willem
, p. 2953 - 2966 (2007/10/03)
The aryl-benzyl cross-coupling in the presence of copper-, nickel- and palladium-catalysts has been investigated with a number of chlorine- and methyl-substituted arylmetal compounds ArM (M = MgBr, ZnCl) and (substituted) benzylic halides ArCH2X. The results have been applied in the selective synthesis of some toxicologically interesting tetrachlorobenzyltoluenes.