51751-11-2Relevant academic research and scientific papers
Zinc-promoted reactions. 8. The effect of ring strain in the reduction of 1,2-dibenzoylcycloalkanes
Di Vona, Maria Luisa,Luchetti, Luciana,Rosnati, Vittorio
, p. 2949 - 2954 (2007/10/02)
Ring cleavage was the main route in the Zn reduction of 1 in neat AcOH, while selective carbonyl reduction predominated in the presence of LiCl. The less strained 2 underwent only carbonyl reduction with Zn/AcOH. The Clemmensen reduction of both 1 and 2 resulted mainly in acyclic products. The unstrained 3 was fairly resistant towards reduction, and did not undergo ring cleavage.
2,2-DIHYDRO 2-METHYL 2,2-DIPHENYL 3,4-METHANO 1,2-OXAPHOSPHOLANNE AS NEW REAGENT FOR THE METHYLENATION OF CARBONYL COMPOUNDS
Daniel, H.,le Corre, M.
, p. 1909 - 1912 (2007/10/02)
2,2-dihydro 2-methyl 2,2-diphenyl 3,4 methano 1,2 oxaphospholanne is effective for the methylenation of carbonyl compounds without base and solvent.
TRIMETHYLSILYL TETRAFLUOROBORATE A CONVENIENT REAGENT FOR SOLVOLYSIS REACTIONS
Caputo, Romualdo,Ferreri, Carla,Palumbo, Giovanni,Wenkert, Ernest
, p. 577 - 578 (2007/10/02)
Conversions of cyclopropyl carbinols (or their acetates) and ketones into homoallyl and γ-substituted ketone derivatives, respectively, are accomplished by trimethylsilyl tetrafluoroborate efficiently and under mild conditions.
FLUORIDE ION INDUCED REACTIONS OF ORGANOSILANES WITH ELECTROPHILES
Ricci, Alfredo,Degl'Innocenti, Alessandro,Fiorenza, Mariella,Taddei, Maurizio,Spartera, Maria A.,Walton, David R.M.
, p. 577 - 578 (2007/10/02)
Benzyl- 4-picolyl- and phenylallyl(trimethyl)silanes react with electrophiles in the presence of KF/18-crown-6 or silica-TBAF under mild conditions.
