517863-80-8

Basic information

• Product Name: [PhONdI₂(THF)4]
• CAS NO: 517863-80-8
• Molecular Weight: 779.582
• Mol File: 517863-80-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [PhONdI₂(THF)4](CAS DataBase Reference)
• NIST Chemistry Reference: [PhONdI₂(THF)4](517863-80-8)
• EPA Substance Registry System: [PhONdI₂(THF)4](517863-80-8)

Safety Data

• Hazardous Substances Data: 517863-80-8(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 108-95-2 phenol 
• 75600-19-0 neodymium(III) iodide hydride 

Relevant articles and documents

Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H

The iodide hydrides NdI2H (1) and DyI2H (2) were obtained by the reactions of diiodides NdI2 (3) and DyI2 (4) with hydrogen at atmospheric pressure and temperature of 120-200 °C. Hydrolysis of products 1 and 2 gives hydrogen in a high yield. The reactions of 1 with phenol and of 2 with isopropyl alcohol in THF afford the iodide phenoxide NdI2(OPh)(THF)4 and iodide isopropoxide DyI 2(OPri)(PriOH)3, respectively. The reaction of 2 with cyclopentadiene is accompanied by disproportionation and gives, besides dihydrogen, Cp2DyI(THF)2 and DyI 3(THF)3.