51803-69-1

Basic information

• Product Name: BOC-VAL-GLY-OME
• Synonyms: BOC-VAL-GLY-OME;Glycine, N-[(1,1-dimethylethoxy)carbonyl]-L-valyl-, methyl ester;methyl (tert-butoxycarbonyl)-L-valylglycinate
• CAS NO: 51803-69-1
• Molecular Formula: C₁₃H₂₄N₂O₅
• Molecular Weight: 288.34
• Mol File: 51803-69-1.mol
• Article Data: 21

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BOC-VAL-GLY-OME(CAS DataBase Reference)
• NIST Chemistry Reference: BOC-VAL-GLY-OME(51803-69-1)
• EPA Substance Registry System: BOC-VAL-GLY-OME(51803-69-1)

Safety Data

• Hazardous Substances Data: 51803-69-1(Hazardous Substances Data)

Upstream product

• 13734-41-3 t-Boc-L-valine 
• 616-34-2 methoxycarbonylmethylamine 
• 5680-79-5 glycine ethyl ester hydrochloride 
• 66866-46-4 C₁₅H₂₇NO₆ 
• 72-18-4 L-valine 
• 24424-99-5 di-tert-butyl dicarbonate 
• 126748-96-7 C₁₈H₃₄N₃O₇P 
• 133010-02-3 1,1-dimethylethyl S-N-(1-fluorocarbonyl-2-methylpropyl)carbamate 

Downstream Products

• 17498-50-9 L-valine hydrochloride 
• 122092-89-1 (3RS,6S)-6-isopropyl-3-methoxy-2,5-piperazinedione 
• 1319113-44-4 (3S,6RS)-3-benzylthio-6-isopropyl-2,5-piperazinedione 

Relevant articles and documents

Single Electron Transfer-Induced Selective α-Oxygenation of Glycine Derivatives

Modification of amino acids is an important strategy in organic and bioorganic chemistry. In contrast to common side-chain functionalization, backbone modification is much less explored. Especially glycine units seem to be attractive and versatile since a wide range of functionality can be potentially introduced. We report here oxidative modification of glycinates that are stable and enable further functionalization. Selective glycinate enolate oxidation by TEMPO or a FeCp2PF6/TEMPO reagent combination provides stable alkoxyamines in good to excellent yields. The methodology is expanded to glycine-containing dipeptides demonstrating selective oxygenation at the glycine unit. The orthogonal reactivity potential of oxygenated glycines for transformation to other amino acid derivatives is explored.

Synthesis and biological evaluation of a novel series of curcumin-peptide derivatives as PepT1-mediated transport drugs

Curcumin (CUR) is a natural yellow pigment from turmeric with extensive bioactivities. However its relatively poor solubility limited its absorption and bioavailability. In this study, a novel series of CUR-peptide conjugates were designed and synthesized

AGRICULTURAL PLANT-PROTECTING AGENTS CONTAINING DIPEPTIDE DERIVATIVE AS ACTIVE INGREDIENT

Provided is an agricultural plant-protecting agent including a dipeptide derivative or an agro-pharmaceutically acceptable salt thereof as an active ingredient, which has a plant disease-preventing effect, a plant growth-promoting effect, and a plant immunity-activating effect.