51861-57-5Relevant articles and documents
A facile method for the synthesis of thiocarbamates: Palladium-catalyzed reaction of disulfide, amine, and carbon monoxide
Nishiyama, Yutaka,Kawamatsu, Hiroaki,Sonoda, Noboru
, p. 2551 - 2554 (2005)
(Equation Presented) A new method for the synthesis of thiocarbamates has been developed. When dialkyl or diaryl disulfides were allowed to react with secondary amines and carbon monoxide in the presence of a catalytic amount of a palladium complex, the thiocarbamates were obtained in moderate to good yields. In contrast to that of secondary amines, in the reaction of a primary amine, no formation of thiocarbamate was confirmed, but urea was formed in good yield.
Palladium-catalyzed insertion reactions of isocyanides into thiocarbamates and selenocarbamates
Shiro, Daisuke,Fujiwara, Shin-Ichi,Tsuda, Susumu,Iwasaki, Takanori,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information, p. 465 - 467 (2015/05/20)
The insertion reaction of isocyanides with thiocarbamates and selenocarbamates in the presence of a Pd(0) catalyst to selectively give 2-oxoethanimidothioates and -selenoates is reported. This is the first example of the insertion of an isocyanide into a
Experimental and theoretical studies on the nucleofugality patterns in the aminolysis and phenolysis of S-Aryl O-Aryl thiocarbonates
Castro, Enrique A.,Aliaga, Margarita,Campodonico, Paola R.,Cepeda, Marjorie,Contreras, Renato,Santos, Jose G.
supporting information; experimental part, p. 9173 - 9179 (2010/03/02)
(Chemical Equation Presented) The reactions of S-phenyl, S-(4-chlorophenyl), and S-(2,3,4,5,6-pentafluorophenyl) 4-nitrophenyl thiocarbonates (9, 11, and 16, respectively) with a series of secondary alicyclic (SA) amines and those of S-(4-methylphenyl) 4-
