51927-46-9

Basic information

• Product Name: Benzene, 1-(bromomethyl)-4-(methylsulfinyl)-
• CAS NO: 51927-46-9
• Molecular Formula: C8H9BrOS
• Molecular Weight: 233.129
• Mol File: 51927-46-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(bromomethyl)-4-(methylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(bromomethyl)-4-(methylsulfinyl)-(51927-46-9)
• EPA Substance Registry System: Benzene, 1-(bromomethyl)-4-(methylsulfinyl)-(51927-46-9)

Safety Data

• Hazardous Substances Data: 51927-46-9(Hazardous Substances Data)

Upstream product

• 3446-90-0 4-(methylthio)benzyl alcohol 
• 38185-19-2 4-(methylthio)benzyl bromide 

Downstream Products

• 145458-70-4 Z(OMe)-Ser(Msib)-OH 
• 129398-69-2 Z(OMe)-Met(O)-OMsib 
• 139300-50-8 Boc-Thr(Msob)-OH 
• 139300-51-9 Boc-Ser(Msob)-OH 
• 129398-76-1 Boc-Tyr(Msib)-OH 
• 129398-73-8 Boc-Tyr(Msib)-Gly-Gly-Phe-Met(O)-OMsib 
• 129398-74-9 Boc-Tyr(Mtb)-Gly-Gly-Phe-Met-OMtb 
• 129398-72-7 Z(OMe)-Gly-Gly-Phe-Met(O)-OMsib 
• 129398-71-6 Z(OMe)-Gly-Phe-Met(O)-OMsib 
• 129398-70-5 Z(OMe)-Phe-Met(O)-OMsib 
• 129398-77-2 Boc-Tyr(Mtb)-OH 
• 129398-78-3 H-Tyr(Msib)-OH 
• 145458-78-2 H-Ser(Msib)-Ala-NH₂*HCl 
• 145458-74-8 Z(OMe)-Ser(Msib)-Ala-NH₂ 

Relevant articles and documents

A general and selective zinc-catalyzed oxidation of sulfides to sulfoxides

A general zinc-catalyzed oxidation of sulfides to sulfoxides has been developed. All the reactions proceeded at room temperature. Hydrogen peroxide was used as a green oxidant. Twenty-one examples of sulfoxides were prepared in moderate to excellent yields.

Sulphur Trioxide/Thiol: A Novel System for the Reduction of Methionine Sulphoxide

A new method for the effective reduction of methionine sulphoxide in protected peptides with sulphur trioxide and thiol has been developed.In practice, a combination of dimethylformamide-sulphur trioxide complex and ethane-1,2-dithiol was found effective, the presence of pyridine in the reaction medium being found necessary for the reduction to proceed.Methionine sulphoxide in two types of protected methionine-enkephalins was efficiently reduced to methionine by this reduction system at 20 deg C in an hour.The (p-methylsulphinyl)benzyl protecting group was also reduced to (p-methylthio)benzyl simultaneously with the reduction of methionine sulphoxide.Subsequent deprotection afforded methionine-enkephalin of high purity in each case.