51934-32-8Relevant academic research and scientific papers
Oxidative ipso -Rearrangement performed by a hypervalent iodine reagent and its application
Jacquemot, Guillaume,Canesi, Sylvain
, p. 7588 - 7594 (2012/10/29)
An oxidative ipso-rearrangement mediated by a hypervalent iodine reagent that enables rapid generation of a functionalized dienone system containing a quaternary carbon center connected to several sp2 centers has been developed. The process occurs through transfer of an aryl group from a silyl segment present on the lateral chain. As an illustration of the potential of this transformation, a total synthesis of sceletenone, a small alkaloid, is described.
