5206-83-7

Basic information

• Product Name: (1R,4R)-(+)-carvomenthone
• Synonyms: (1R,4R)-(+)-carvomenthone
• CAS NO: 5206-83-7
• Molecular Weight: 154.252
• Mol File: 5206-83-7.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: (1R,4R)-(+)-carvomenthone(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R)-(+)-carvomenthone(5206-83-7)
• EPA Substance Registry System: (1R,4R)-(+)-carvomenthone(5206-83-7)

Safety Data

• Hazardous Substances Data: 5206-83-7(Hazardous Substances Data)

Upstream product

• 33375-08-5 (R)-5-isopropyl-2-methylcyclohex-2-enone 
• 1195-31-9 (+)-p-menth-1-ene 
• 499-75-2 carvacrol 
• 10309-68-9 (+)-4-trans-isopropenyl-1-methylbicyclo<3.1.0>hexan-2-one 
• 99-49-0 Carvone 
• 4017-88-3 (+/-)-cis-caran-trans-4-ol 
• 3792-53-8 2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 23733-68-8 p-menth-3-en-2-one 
• 4031-57-6 (1RS,2SR,4SR)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2SR,4RS)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2RS,4SR)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2RS,4RS)-p-menthane-1,2-diol 
• 74006-76-1 (R)-(+)-3-(1-methylethyl)cyclohexanone 
• 74-88-4 methyl iodide 

Downstream Products

• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 499-69-4 5-isoprpyl-2-methylcyclohexan-1-ol 
• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 59060-39-8 hydroxymethylenecarvomenthone 
• 606490-81-7 (4R,7R)-(-)-7-methyl-4-isopropyl-2-oxo-oxepanone 
• 141538-91-2 (3R,6S)-(-)-3-methyl-6-iso-propenyl-2-oxo-oxepanone 
• 127825-79-0 3-<4-Isopropyl-1-methyl-2-oxo-cyclohexyl-(1)>-propionsaeure 
• 140924-67-0 (1S,2S,3R,6S)-3-methyl-6-(methylethyl)cyclohexane-1,2-diol 

Relevant articles and documents

Selective C-C Bond Cleavage of Cycloalkanones by NaNO2/HCl

A novel selective fragmentation of cycloalkanones by NaNO2/HCl has been established. The C-C bond cleavage reaction proceeds smoothly under mild conditions, selectively affording versatile keto acids or oxime acids. The methodology can streamline the synthesis of valuable chiral molecules and isocoumarins from readily available feedstocks.

Environmentally responsible, safe, and chemoselective catalytic hydrogenation of olefins: ppm level Pd catalysis in recyclable water at room temperature

Textbook catalytic hydrogenations are typically presented as reactions done in organic solvents and oftentimes under varying pressures of hydrogen using specialized equipment. Catalysts new and old are all used under similar conditions that no longer reflect the times. By definition, such reactions are both environmentally irresponsible and dangerous, especially at industrial scales. We now report on a general method for chemoselective and safe hydrogenation of olefins in water using ppm loadings of palladium from commercially available, inexpensive, and recyclable Pd/C, together with hydrogen gas utilized at 1 atmosphere. A variety of alkenes is amenable to reduction, including terminal, highly substituted internal, and variously conjugated arrays. In most cases, only 500 ppm of heterogeneous Pd/C is sufficient, enabled by micellar catalysis used in recyclable water at room temperature. Comparison with several newly introduced catalysts featuring base metals illustrates the superiority of chemistry in water.

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Air-stable Rh complexes ligated by strongly σ-donating cyclic (amino)(alkyl)carbenes (CAACs) show unique catalytic activity for the selective hydrogenation of aromatic ketones and phenols by reducing the aryl groups. The use of CAAC ligands is essential for achieving high selectivity and conversion. This method is characterized by its good compatibility with unsaturated ketones, esters, carboxylic acids, amides, and amino acids and is scalable without detriment to its efficiency.