52121-66-1Relevant articles and documents
Nickel-catalyzed guerbet type reaction: C-alkylation of secondary alcohols via double (de)hydrogenation
Babu, Reshma,Subaramanian, Murugan,Midya, Siba P.,Balaraman, Ekambaram
supporting information, p. 3320 - 3325 (2021/05/31)
Acceptorless double dehydrogenative cross-coupling of secondary and primary alcohols under nickel catalysis is reported. This Guerbet type reaction provides an atom- and a step-economical method for the C-alkylation of secondary alcohols under mild, benign conditions. A broad range of substrates including aromatic, cyclic, acyclic, and aliphatic alcohols was well tolerated. Interestingly, the C-alkylation of cholesterol derivatives and the double C-alkylation of cyclopentanol with various alcohols were also demonstrated.
Aryl substituted diketones
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, (2008/06/13)
Aryl substituted diketones and keto-esters, useful as antiviral agents and insecticides, are prepared by reacting an arylalkyl or arylalkenyl iodide with a metal salt of the appropriate diketone or keto-ester.
Methylenedioxyphenyl substituted aliphatic diketones
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, (2008/06/13)
Aryl substituted diketones and keto-esters, useful as antiviral agents and insecticides, are prepared by reacting an arylalkyl or arylalkenyl iodide with a metal salt of the appropriate diketone or keto-ester.