52123-67-8Relevant academic research and scientific papers
SYNTHESIS OF 1-TERT-BUTYL-2-ARYLDIAZENE-2-OXIDES BY REACTION OF t-BuNHMgBr WITH NITROBENZENES
Apasov, E. T.,Dzhetigenov, B. A.,Strelenko, Yu. A.,Kalinin, A. V.,Tartakovskii, V. A.
, p. 1234 - 1238 (2007/10/02)
A new method has been developed for the synthesis of alkylaryldiazene oxides by the reactions of t-BuNHMgBr with nitrobenzenes.The cis-azoxy compound 1-tert-butyl-2-(2-chlorophenyl)diazene-2-oxide, which irreversibly isomerizes to the trans isomer upon he
N-LITHIUM DERIVATIVES OF ALIPHATIC AMINES IN THE SYNTHESIS OF 1-ALKYL-2-PHENYLDIAZENE 2-OXIDES
Shepelev, E. V.,Kostikova, N. N.,Dzhetigenov, B. A.,Kalinin, A. V.
, p. 1291 - 1293 (2007/10/02)
Magnesium derivatives of aliphatic amines containing α-hydrogen atoms, in contrast to t-BuNHMgBr, do not form phenylaliphatic diazene oxides upon reaction with nitrobenzene, but rather reduce it to azobenzene and azoxybenzene.Asymmetric diazene oxides are formed when the magnesium derivatives are replaced by lithium derivatives.The reaction of t-BuNHLi with dimethylnitramine gives 1,3,5-trimethyl-1,3,5-triazacyclohexane.
Hypervalent Iodine Oxidation of Amines in the Presence of Nitroso Compounds: A Method for the Preparation of Unsymmetrically Substituted Azoxy Compounds
Moriarty, R.M.,Hopkins, T.E.,Prakash, I.,Vaid, B.K.,Vaid, R.K.
, p. 2353 - 2357 (2007/10/02)
Various amines and amino derivatives such as (tert-butylamine, 4-amino-1,2,4-triazole-p-toluenesulfonamide), and cyanamide, when treated with benzene in the presence of nitroso compounds (2) yield unsymmetrically substituted azoxy compoun
