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52189-36-3

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52189-36-3 Usage

General Description

3-Acetylamino-benzoic acid methyl ester is a chemical compound with the molecular formula C10H11NO3. It is a derivative of benzoic acid and is commonly used in organic synthesis and pharmaceutical research. 3-Acetylamino-benzoic acid methyl ester is a white crystalline powder and is typically prepared by the reaction of acetic anhydride with 3-aminobenzoic acid, followed by esterification with methanol. 3-Acetylamino-benzoic acid methyl ester has various applications in the production of pharmaceuticals and agrochemicals, as well as in the development of new materials and polymers. It is also used as a building block in the synthesis of other organic compounds. Additionally, it is known to have analgesic and anti-inflammatory properties, making it of interest for potential medical uses.

Check Digit Verification of cas no

The CAS Registry Mumber 52189-36-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,1,8 and 9 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 52189-36:
(7*5)+(6*2)+(5*1)+(4*8)+(3*9)+(2*3)+(1*6)=123
123 % 10 = 3
So 52189-36-3 is a valid CAS Registry Number.

52189-36-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name Methyl 3-acetamidobenzoate

1.2 Other means of identification

Product number -
Other names HMS1434H03

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:52189-36-3 SDS

52189-36-3Relevant articles and documents

Catalyst-free generation of acyl radicals induced by visible light in water to construct C-N bonds

Ran, Maogang,He, Jiaxin,Yan, Boyu,Liu, Wenbo,Li, Yi,Fu, Yunfen,Li, Chao-Jun,Yao, Qiuli

supporting information, p. 1970 - 1975 (2021/03/16)

We describe herein a catalyst-free and redox-neutral photochemical strategy for the direct generation of acyl radicals from α-diketones, and its selective conversion of nitrosoarenes to hydroxyamides or amides with AcOH or NaCl as an additive. The reaction was carried out under mild conditions in water with purple LEDs as the light source. A broad scope of substrates was demonstrated. Mechanistic experiments indicate that α-diketones cleave to give acyl radicals, with hydroxyamides being further reduced to amides.

Selectivity, ligand deconstruction, and cellular activity analysis of a BPTF bromodomain inhibitor

Kirberger, Steven E.,Ycas, Peter D.,Johnson, Jorden A.,Chen, Chen,Ciccone, Michael F.,Woo, Rinette W. L.,Urick, Andrew K.,Zahid, Huda,Shi, Ke,Aihara, Hideki,McAllister, Sean D.,Kashani-Sabet, Mohammed,Shi, Junwei,Dickson, Alex,Dos Santos, Camila O.,Pomerantz, William C. K.

supporting information, p. 2020 - 2027 (2019/02/20)

Bromodomain and PHD finger containing protein transcription factor (BPTF) is an epigenetic protein involved in chromatin remodelling and is a potential anticancer target. The BPTF bromodomain has one reported small molecule inhibitor (AU1, rac-1). Here, advances made on the structure-activity relationship of a BPTF bromodomain ligand are reported using a combination of experimental and molecular dynamics simulations leading to the active enatiomer (S)-1. Additionally, a ligand deconstruction analysis was conducted to characterize important pharmacophores for engaging the BPTF bromodomain. These studies have been enabled by a protein-based fluorine NMR approach, highlighting the versatility of the method for selectivity, ligand deconstruction, and ligand binding. To enable future analysis of biological activity, cell growth analyses in a panel of cancer cell lines were carried out using CRISPR-Cas9 and (S)-1 to identify cell-based model systems that are sensitive to BPTF inhibition.

Mild and efficient palladium-catalyzed direct trifluoroethylation of aromatic systems by C-H activation

T?th, Balázs L.,Kovács, Szabolcs,Sályi, Gerg?,Novák, Zoltán

supporting information, p. 1988 - 1992 (2016/02/18)

The introduction of trifluoroalkyl groups into aromatic molecules is an important transformation in the field of organic and medicinal chemistry. However, the direct installation of fluoroalkyl groups onto aromatic molecules still represents a challenging and highly demanding synthetic task. Herein, a simple trifluoroethylation process that relies on the palladium-catalyzed C-H activation of aromatic compounds is described. With the utilization of a highly active trifluoroethyl(mesityl)iodonium salt, the developed catalytic method enables the first highly efficient and selective trifluoroethylation of aromatic compounds. The robust catalytic procedure provides the desired products in up to 95 % yield at 25 °C in 1.5 to 3 hours and tolerates a broad range of functional groups. The utilization of hypervalent reagents opens new synthetic possibilities for direct alkylations and fluoroalkylations in the field of transition-metal-catalyzed C-H activation.

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