79044-00-1

Basic information

• Product Name: 3-Acetylamino-4-((E)-3-oxo-but-1-enyl)-benzoic acid methyl ester
• CAS NO: 79044-00-1
• Molecular Weight: 261.277
• Mol File: 79044-00-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Acetylamino-4-((E)-3-oxo-but-1-enyl)-benzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Acetylamino-4-((E)-3-oxo-but-1-enyl)-benzoic acid methyl ester(79044-00-1)
• EPA Substance Registry System: 3-Acetylamino-4-((E)-3-oxo-but-1-enyl)-benzoic acid methyl ester(79044-00-1)

Safety Data

• Hazardous Substances Data: 79044-00-1(Hazardous Substances Data)

Upstream product

• 52189-36-3 methyl 5-acetylaminobenzoate 
• 78-94-4 methyl vinyl ketone 

Relevant articles and documents

Ortho Vinylation of Aromatic Amides via Cyclopalladation Complexes

The reaction of acetanilide and meta- and para-substituted acetanilides with palladium acetate has given new ortho-palladated complexes 2a-j, which reacted with carbon monoxide, ethylene, or methyl vinyl ketone to produce the corresponding N-acylanthranilic esters 4a-m, 2-acetaminostyrenes 9k-p, and 4-aryl-3-buten-2-one derivatives 9a-j, respectively.Reactions of 2a with substituted olefins proceeded readily to give the 2-olefins 8a-h.Ortho-substituted acetanilides and N-methylacetanilide did not undergo complex formation with palladium acetate.