52246-10-3Relevant academic research and scientific papers
Concise synthesis of photocleavable molecular tag for laser desorption ionization mass spectrometry via fries reaction
Gathirwa, Jeremiah W.,Maki, Toshihide
, p. 1016 - 1022 (2013/02/25)
A new synthetic route for the photocleavable molecular tag for laser desorption ionization mass spectrometry (LDI-MS) was achieved using the Fries reaction of 2,6-dimethylphenyl ester as its key reaction. Zirconium chloride was used as uniquely efficient
Photocleavable molecule for laser desorption ionization mass spectrometry
Maki, Toshihide,Ishida, Koji
, p. 6427 - 6433 (2008/02/10)
(Figure Presented) A new photocleavable molecule for laser desorption ionization mass spectrometry (LDI-MS) was designed and synthesized. The molecule exhibited high sensitivity for negative mode MS detection with good chemical stability. The molecule was successfully applied to molecular tag for (LDI-MS). Kinetic measurement of the amidation reaction and monitoring of aminolysis of acetylated sugars were demonstrated with the molecular tag.
