5227-59-8Relevant academic research and scientific papers
Synthesis, crystal structure and calculation of oxides of 2-methylamino-3-methyl quinoxaline
Li, Junjian,Wang, Rui,Wang, Wenfeng,Wang, Xucheng,Yuan, Yaofeng,Zhang, Min
, (2020/07/27)
Monoxide and dioxide of animo quinoxaline were synthesized and characterized by 1H NMR, 13C NMR and HRMS. The result shows that monoxide is main product. 1H NMR analysis, quantum calculation and crystal structure all indicate that the monoxide is 4-oxide structure but not 1-oxide structure. The subsequent discussions of electronic effect and steric effect of 1-oxide and 4-oxide support the conclusion that 4-oxide is dominant product, which is consistent with 1H NMR analysis and crystal structure. At last, the calculated structure is in good agreement with the crystal structure in this paper, which indicates that the calculation result in this paper is credible.
First synthesis of 2-phosphonylated quinoxaline 1,4-dioxides: An extension to the Beirut reaction
Dahbi, Samir,Methnani, Ebtissem,Bisseret, Philippe
scheme or table, p. 5516 - 5520 (2010/10/21)
An extension of the Beirut reaction for the preparation of the first members of the 2-phosphonylated quinoxaline 1,4-dioxide series is described. Contrary to their carboxylated equivalents, preparation of these new compounds could not be achieved under basic conditions but required the use of powdered molecular sieves. Good and reproducible yields were obtained only when the initial suspension in THF was transformed into a pasty film by slow evaporation of ca. 90% of the initial solvent volume.
A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF·CH3CN
Carmeli, Mira,Rozen, Shlomo
, p. 5761 - 5765 (2007/10/03)
HOF·CH3CN, a very efficient oxygen-transfer agent made readily from fluorine and aqueous acetonitrile, was reacted with various quinoxaline derivatives to give the corresponding mono N-oxides and especially the N,N′-dioxides in very good yields under mild conditions and short reaction times.
Tetrazolo(1,5-a)quinoxalines for control of phytopathogens
-
, (2008/06/13)
The protection of plants from foliar and soil-borne phytopathogens is accomplished by the treatment of the plants with a specified class of tetrazolo[1,5-a]quinoxalines.
