52326-08-6Relevant articles and documents
Synthesis of benzothiazine sulfonamides via heteroatomic Diels-Alder reaction of para-fluoro-N-sulfinylaniline with bicyclo[2.2.1]heptenes
Veremeichik,Shurpik,Lodochnikova,Plemenkov
, p. 296 - 299 (2016)
Reaction of 4-fluoro-N-sulfinylaniline with norbornene and norbornadiene has afforded the Diels-Alder adducts of benzothiazine structure that have been oxidized into the corresponding benzothiazine sulfonamides. Structure of the obtained compounds and ste
Synthesis, characterization and vibrational properties of p-fluorosulfinylaniline
Jerez, Ana L. Pez,Antognini, Andrea Flores,Cutin, Edgardo H.,Robles, Norma L.
, p. 300 - 305 (2015)
The reaction of p-fluoroaniline and SOCl2 rendered p-fluorosulfinylaniline in good yield. The obtained dark yellowish liquid compound was characterized by NMR, UV-visible, FT-IR and Raman spectroscopies. The observed features were consistent wi
Synthesis of six-membered cyclic sulfonimidamides
Sen, Indira,Kloer, Daniel,Hall, Roger,Pal, Sitaram
, p. 3018 - 3028 (2013/11/06)
A general synthetic route to six-membered cyclic N-aryl- and N-alkyl-substituted sulfonimidamides via an intramolecular ring closure of suitably functionalised acyclic sulfonimidamides is described. The structure of this new ring system was confirmed by v
N-heterocyclic carbene catalysis: Enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines
Jian, Teng-Yue,He, Lin,Tang, Cen,Ye, Song
supporting information; body text, p. 9104 - 9107 (2011/10/13)
Sultam of swing: Both enantiomers of 1,2-thiazetidin-3-one oxides were obtained in very good yields with excellent enantioselectivities when using N-heterocyclic carbene catalysts (see scheme; M.S.=molecular sieves, TBS=tert-butyldimethylsilyl). The products were easily converted into 3-oxo-β-sultams, α-mercapto amides, and β-mercapto amines through oxidation or reduction. Copyright
Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]
Baudin, Jean-Bernard,Commenil, Marie-Gabrielle,Julia, Sylvestre A.,Lorne, Robert,Mauclaire, Laurent
, p. 329 - 350 (2007/10/03)
Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.
Reactions of N-sulfinylfluoroalkanesulfonyl amines with nucleophiles containing reactive hydrogen
Li, Ai-Wen,Xu, Bin,Wang, Chao-Xian,Zhu, Shi-Zheng
, p. 85 - 88 (2007/10/02)
The reactions of N-sulfinylfluoroalkanesulfonyl amines, RfSO2NSO (1), with malonate or dialkyl phosphite gave 1:1 adducts RfSO2NHS(O)Nu , and with alcohols or phenols formed RfSO2NH2 and the sulfites O=S(OR)2 by double addition .Trans-sulfinylation occurred during the reaction of 1 with anilines (C6H5NH2, 4-FC6H4NH2 and C6F5NH2).
Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekuelen, XXVI Reaktionen von N-Sulfinylverbindungen mit Thioboranen
Meller, Anton,Maringgele, Walter,Fetzer, Hartmut
, p. 1950 - 1961 (2007/10/02)
The reaction of N-sulfinylamines with (methylthio)organylboranes proceeds quantitatively according to R-N=S=O + 3 R'2BSCH3 -> RN(BR'2)-SSCH3 + CH3SSCH3 + 2O by insertion of the N=S double bond into the B-S sequence and a complex redox-reaction.Th