52403-06-2Relevant academic research and scientific papers
Cu-Catalyzed Oxidative Thioesterification of Aroylhydrazides with Disulfides
Xie, Shimin,Su, Lebin,Mo, Min,Zhou, Wang,Zhou, Yongbo,Dong, Jianyu
supporting information, p. 739 - 749 (2021/01/09)
An alternative thioesterification reaction via copper-catalyzed oxidative coupling of readily available aroylhydrazides with disulfides is developed, in which oxidative expulsion of N2 overcomes the activation barrier between the carboxylic acid derivativ
Copper-Catalyzed Three-Component One-Pot Synthesis of Aryl Sulfides with Sulfur Powder under Aqueous Conditions
Xiao, Fuhong,Chen, Shuqing,Li, Cheng,Huang, Huawen,Deng, Guo-Jun
supporting information, p. 3881 - 3886 (2016/12/16)
A copper-catalyzed three-component (arenes, iodohydrocarbon, and sulfur powder) synthesis of substituted aryl sulfides has been developed. Water is used as the green solvent in a simple and environmentally friendly procedure. Various functional groups attached to the substrates were well tolerated in this process to afford the corresponding products in moderate to good yields. (Figure presented.).
Electrical Conduction in Copper(I) Mercaptide Complexes of Aromatic and Heteroaromatic Mercaptans
Prakash, Hari
, p. 709 - 712 (2007/10/02)
Electrical conductivities of copper(I) mercaptide complexes of aromatic and heteroaromatic mercaptans have been measured and a conduction mechanism is discussed.The observed conductivities are highly substitution-dependent and vary in the range of 1E-4 to 1E-10 ohm-1 cm-1 at 25 deg C.The solid state absorption spectra and the pressure-induced colour change of the complexes indicate creation of mixed-valence Cu(I)-Cu(II) species which appear to be responsible for their relatively high conductivities.A model which assumes electron hopping assisted by Cu-S stretching frequency along the -Cu-S-Cu-S- conducting spine formed in the S-bridged polymeric structures of these complexes is suggested for the conduction process.
