52455-72-8

Basic information

• Product Name: 2-BENZYLIDENEQUINUCLIDIN-3-ONE
• Synonyms: 2-BENZYLIDENEQUINUCLIDIN-3-ONE
• CAS NO: 52455-72-8
• Molecular Formula: C₁₄H₁₅NO
• Molecular Weight: 213.27
• Mol File: 52455-72-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-BENZYLIDENEQUINUCLIDIN-3-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BENZYLIDENEQUINUCLIDIN-3-ONE(52455-72-8)
• EPA Substance Registry System: 2-BENZYLIDENEQUINUCLIDIN-3-ONE(52455-72-8)

Safety Data

• Hazardous Substances Data: 52455-72-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 1193-65-3 3-quinuclidinone hydrochloride 
• 24123-89-5 (Z)-2-benzylidene-1-azabicyclo[2.2.2]octan-3-one 

Downstream Products

• 112611-41-3 2-[1-Phenyl-meth-(E)-ylidene]-1-aza-bicyclo[2.2.2]octan-3-ol 

Relevant articles and documents

Mutual Z-/E-isomerization of ferrocenylmethylene- and arylidene-substituted carbo- and heterocycles

The treatment of Z-2-ferrocenylmethylene-, Z-2-arylidene-3-quinuclidinones and 3-methylene-quinuclidines, as well as E-3-ferrocenylmethylenecamphor, -menthone, and -cyclohexanone with NaBPh4 in acetic acid results in their reversible Z-/E-isomerization. The reaction proceeds via hydroxyallyl and crotyl carbocations with a fixed s-cis-conformation.