52456-99-2Relevant articles and documents
Cyclopropane-alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes
Mato, Mauro,Martín-Torres, Inmaculada,Herlé, Bart,Echavarren, Antonio M.
, p. 4216 - 4219 (2019/05/06)
A gold(i)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent
Stereoselective preparation of cyclopropylmagnesium reagents via a Br-Mg exchange using i-PrMgCl·LiCl in the presence of dioxane
Rauhut, Christian B.,Cervino, Christian,Krasovskiy, Arkady,Knochel, Paul
scheme or table, p. 67 - 70 (2009/05/28)
The reaction of various cyclopropyl bromides with i-PrMgCl·LiCl in THF-dioxane provides the corresponding magnesiated cyclopropane reagents with complete retention of configuration. Georg Thieme Verlag Stuttgart.