52456-99-2Relevant articles and documents
Cyclopropane-alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes
Mato, Mauro,Martín-Torres, Inmaculada,Herlé, Bart,Echavarren, Antonio M.
, p. 4216 - 4219 (2019/05/06)
A gold(i)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent
Spin-selective generation of triplet nitrenes: Olefin aziridination through visible-light photosensitization of azidoformates
Scholz, Spencer O.,Farney, Elliot P.,Kim, Sangyun,Bates, Desiree M.,Yoon, Tehshik P.
, p. 2239 - 2242 (2016/02/18)
Azidoformates are interesting potential nitrene precursors, but their direct photochemical activation can result in competitive formation of aziridination and allylic amination products. Herein, we show that visible-light-activated transition-metal comple
Stereoselective preparation of cyclopropylmagnesium reagents via a Br-Mg exchange using i-PrMgCl·LiCl in the presence of dioxane
Rauhut, Christian B.,Cervino, Christian,Krasovskiy, Arkady,Knochel, Paul
scheme or table, p. 67 - 70 (2009/05/28)
The reaction of various cyclopropyl bromides with i-PrMgCl·LiCl in THF-dioxane provides the corresponding magnesiated cyclopropane reagents with complete retention of configuration. Georg Thieme Verlag Stuttgart.
SYNTHESIS OF STEREOISOMERIC 1-HYDROXYMETHYL-2,3-DIALKYL(DIPHENYL)CYCLOPROPANES AND 1-FORMYL-2,3-DIALKYL(DIPHENYL)CYCLOPROPANES
Komendantov, M.I.,Panasyuk, T.B.
, p. 1308 - 1312 (2007/10/02)
Lithium aluminum hydride reduction of stereoisomeric 2,3-dipropyl(diphenyl)cyclopropanecarboxylic acid esters results in the formation of stereoisomeric 1-hydroxymethyl-2,3-dipropyl(diphenyl)cyclopropanes, which can be oxidized to the corresponding stereo
