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7381-90-0

Cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane is a complex organic compound with the molecular formula C17H16O. It is characterized by a cyclopropane ring, which consists of three carbon atoms bonded in a triangular arrangement. The molecule features two phenyl groups (C6H5) attached to the second and third carbon atoms of the cyclopropane ring, and a hydroxymethyl group (-CH2OH) attached to the first carbon atom. The "cis, cis" configuration indicates that both phenyl groups and the hydroxymethyl group are on the same side of the cyclopropane ring. cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane is of interest in organic chemistry due to its unique structure and potential applications in the synthesis of other complex molecules.

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  • 7381-90-0 Structure

  • Basic information

    1. Product Name: cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane
    2. Synonyms: cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane
    3. CAS NO:7381-90-0
    4. Molecular Formula:
    5. Molecular Weight: 224.302
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 7381-90-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane(CAS DataBase Reference)
    10. NIST Chemistry Reference: cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane(7381-90-0)
    11. EPA Substance Registry System: cis, cis-1-hydroxymethyl-2,3-diphenylcyclopropane(7381-90-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 7381-90-0(Hazardous Substances Data)

7381-90-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7381-90-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,8 and 1 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 7381-90:
(6*7)+(5*3)+(4*8)+(3*1)+(2*9)+(1*0)=110
110 % 10 = 0
So 7381-90-0 is a valid CAS Registry Number.

7381-90-0Relevant articles and documents

Cyclopropane-alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

Mato, Mauro,Martín-Torres, Inmaculada,Herlé, Bart,Echavarren, Antonio M.

supporting information, p. 4216 - 4219 (2019/05/06)

A gold(i)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent

Diastereoselective borocyclopropanation of allylic ethers using a boromethylzinc carbenoid

Benoit, Guillaume,Charette, André B.

, p. 1364 - 1367 (2017/02/10)

A borocyclopropanation of (E)- and (Z)-allylic ethers and styrene derivatives via the Simmons-Smith reaction using a novel boromethylzinc carbenoid is described. The carbenoid precursor is prepared via a 3-step sequence from inexpensive and commercially available starting materials. This methodology allows for the preparation of 1,2,3-substituted borocyclopropanes in high yields and diastereoselectivities. Several postfunction-alization reactions were also performed to illustrate the versatility of these building blocks.

Spin-selective generation of triplet nitrenes: Olefin aziridination through visible-light photosensitization of azidoformates

Scholz, Spencer O.,Farney, Elliot P.,Kim, Sangyun,Bates, Desiree M.,Yoon, Tehshik P.

supporting information, p. 2239 - 2242 (2016/02/18)

Azidoformates are interesting potential nitrene precursors, but their direct photochemical activation can result in competitive formation of aziridination and allylic amination products. Herein, we show that visible-light-activated transition-metal comple

Enantioselective synthesis of 1,2,3-trisubstituted cyclopropanes using gem-dizinc reagents

Zimmer, Lucie E.,Charette, Andre B.

supporting information; experimental part, p. 15624 - 15626 (2010/01/30)

(Chemical Equation Presented) The first asymmetric cyclopropanation of allylic alcohols using gem-dizinc carbenoids, which allows the synthesis of 1,2,3-substituted cyclopropane derivatives in high yields and excellent enantio- and diastereoselectivities,

SYNTHESIS OF STEREOISOMERIC 1-HYDROXYMETHYL-2,3-DIALKYL(DIPHENYL)CYCLOPROPANES AND 1-FORMYL-2,3-DIALKYL(DIPHENYL)CYCLOPROPANES

Komendantov, M.I.,Panasyuk, T.B.

, p. 1308 - 1312 (2007/10/02)

Lithium aluminum hydride reduction of stereoisomeric 2,3-dipropyl(diphenyl)cyclopropanecarboxylic acid esters results in the formation of stereoisomeric 1-hydroxymethyl-2,3-dipropyl(diphenyl)cyclopropanes, which can be oxidized to the corresponding stereo

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