52460-85-2

Upstream product

• 86-29-3 Diphenylacetonitrile 

Downstream Products

• 52044-68-5 benzoyloxy-diphenyl-acetonitrile 
• 6639-43-6 2,2,2-triphenylacetonitrile 
• 52460-99-8 amino-diphenyl-acetonitrile 
• 51065-40-8 α-azidodiphenylacetonitrile 
• 98888-97-2 1,1-Diphenyl-1-piperidino-acetonitril 
• 940002-33-5 (5,10,15,20-tetramesitylporphyrinato)bromo rhodium(III) 
• 3060-50-2 2,2-diphenylglycine 
• 102891-98-5 (benzoylamino-diphenyl-acetoxy)-acetic acid ethyl ester 
• 101721-34-0 (azido-diphenyl-acetoxy)-acetic acid ethyl ester 
• 101730-38-5 (amino-diphenyl-acetoxy)-acetic acid ethyl ester 
• 101101-79-5 methyl 2-azido-2,2-diphenylacetate 
• 2571-41-7 azido-diphenyl-acetic acid 
• 15427-81-3 α-amino-α,α-diphenylacetamide 
• 41601-09-6 5,5-diphenyl-1,5-dihydro-[1,2,3]triazol-4-one 

Relevant academic research and scientific papers

Unexpected Staudinger reaction of α-azidoacetonitriles α-phenyl substituted with triphenylphospine. Preparation, X-ray crystal and molecular structures of a phosphazine, an aminophosphonium carbanion salt and a phosphazide, with (Z)-configuration

Staudinger reaction of α-azidophenylacetonitrile with triphenylphosphine in 1:2 molar ratio provides the triphenylphosphazine 4 derived from α-diazophenylacetonitrile, whereas 2:1 molar ratio the final product is found to be the aminotriphenylphosphonium salt of phenylmalononitrile 6. However, the Staudinger reaction of α- azidodiphenylacetonitrile with triphenylphosphine affords the corresponding (Z)-phosphazide 17. The crystal and molecular structures of compounds 4,6, and 17 have been determined by X-ray analysis. Compound 17 is the first isolated phosphazide which presents the (Z)-configuration with respect to the central N,N bond of the PN3C moiety (P-N-N-N= 0.0(3)°).