5251-70-7Relevant academic research and scientific papers
Kinetics of reaction of cyanoisopropylperoxy radicals with divalent manganese in acetic acid
Adamyan,Geletii,Popova,Zakharov
, p. 1307 - 1310 (2008/10/08)
The kinetics of the reaction of cyanoisopropylperoxy radicals with Mn(II) acetate in acetic acid at a temperature of 70°C, leading to the formation of a hydroperoxide, was studied by the chemiluminescent method. It was found that the effective rate constant of this reaction decreases with increase in the concentration of Mn(II) approximately according to the relationship keff approximately [Mn(II)]-1 from 9.104 to 1.104 liter/mole·sec when [Mn(II)] increases from 10-4 to 10-3 mole/liter. A scheme was proposed for the reaction of RO2· with Mn(II) via the formation of an intermediate complex RO2 -Mn3+. The observed decrease in keff is explained by the inactivation of the complex by its reaction with a free Mn(II) ion.
