52554-66-2Relevant academic research and scientific papers
Trans influence of triphenylstibine. Crystal and molecular structures of cis-[PtCl2 (SbPh3)2] and trans-[PtI2 (SbPh3)2]
Wendt, Ola F.,Scodinu, Alessandra,Elding, Lars I.
, p. 237 - 241 (2008/10/08)
Crystals of cis-[PtCl2(SbPh3)2] (1) are monoclinic, space group P21/a with a=20.5708(12), b=10.1942(4), c=33.3984(15) A, β=94.394(4)° and Z= 8. Substitution of chloride for iodide yields trans-[Ptl2(SbPh3)2] (2), the crystals of which are monoclinic, space group P21/c with a=18.108(4), b=10.102(2), c=19.115(5) A, β=95.241(16)° and Z=4. The average Pt-Cl distance in 1 is 2.338(12) A, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.
The preparation and properties of some triphenylarsine- and triphenylstibine-stabilized organoplatinum(II) compounds
Kistner,Blackman, Jon D.,Harris, William C.
, p. 2165 - 2167 (2007/11/06)
The reaction of alkyl- and arylplatinum(II)-olefin complexes with triphenylarsine and triphenylstibine yields a series of compounds of the type L2PtR2, where L is(C6H5)8As or (C6H5)8Sb and R is a σ-bonded aryl or alkyl group. The properties of these compounds differ with the size of the stabilizing ligand and the position of substitution on the benzene ring. These properties are reported and discussed.
Inorganic linkage isomerism of the thiocyanate ion
Burmeister, John L.,Basolo, Fred
, p. 1587 - 1593 (2008/10/08)
Linkage isomers of metal complexes of the type M-SCN (thiocyanato) and M-NCS (isothiocyanato) are reported for the compounds [Pd(As(C6H5)3)2X2] and [Pd(bipy)X2]. The method of preparation d
