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Usage

Uses

Used in Pharmaceutical Industry:
1-CHLOROMETHYL-4-METHYLNAPHTHALENE is used as a chemical intermediate for the synthesis of various pharmaceutical products, contributing to the development of new medications and therapeutic agents.
Used in Fragrance Industry:
1-CHLOROMETHYL-4-METHYLNAPHTHALENE is used as a precursor in the production of fragrances, leveraging its strong odor to create a variety of scent profiles for different applications.
Used in Dye Industry:
1-CHLOROMETHYL-4-METHYLNAPHTHALENE is used as a starting material in the synthesis of dyes, playing a crucial role in the development of colorants for textiles, plastics, and other materials.
Used in Chemical Production:
1-CHLOROMETHYL-4-METHYLNAPHTHALENE is used as an intermediate in the production of various chemicals, facilitating the creation of a wide range of chemical compounds for diverse industrial applications.

InChI:InChI=1/C19H23FN2/c1-15-3-4-17(16(2)13-15)14-21-9-11-22(12-10-21)19-7-5-18(20)6-8-19/h3-8,13H,9-12,14H2,1-2H3

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 90-12-0 1-Methylnaphthalene 
• 50-00-0 formaldehyd 
• 57322-44-8 4-methylnaphthalene-1-methanol 
• 7647-01-0 hydrogenchloride 
• 64-19-7 acetic acid 
• 35461-84-8 1,4-epidioxy-1,4-dimethyl-1,4-dihydroxynaphthalene 
• 35461-84-8 1,4-dimethylnaphtalene-1,4-endoperoxide 

Downstream Products

• 476-73-3 1,2,3,4-benzenetetracaboxylic acid 
• 605-70-9 naphthalene-1,4-dicarboxylic acid 
• 58791-49-4 1,4-bis(bromomethyl)naphthalene 
• 34163-22-9 (1,4-dimethylnaphthalen-2-yl)(phenyl)methanone 
• 1442483-03-5 2-((4-methylnaphthalen-1-yl)methyl)-2-(1-phenylbut-3-en-1-yl)malononitrile 
• 1421365-48-1 C₂₃H₁₉ClN₂O₃ 
• 1221432-92-3 1-methyl-4-methylene-1-(propa-1,2-dienyl)-1,4-dihydronaphthalene 
• 1221432-91-2 1-methyl-4-methylene-1-(prop-2-ynyl)-1,4-dihydronaphthalene 
• 4488-40-8 4-Methyl-1-naphthoic acid 
• 97586-02-2 1-(1-naphthyl)-2-(4-methyl-1-naphthyl)ethene, trans isomer 
• 97585-87-0 (4-Methyl-naphthalen-1-ylmethyl)-triphenyl-phosphonium; chloride 
• 571-58-4 1,4-dimethylnaphthalene 
• 71235-76-2 1-methoxymethyl-4-methylnaphthalenen 

Relevant academic research and scientific papers

Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane

A dearomative C4-allylation of benzyl ammoniums with allyltributylstannane by a palladium catalysis is described. A triarylphosphine-ligated palladium catalyst, which is capable of cleaving benzylic CN bonds, realized facile dearomative reactions with C4 selectivity. Combined with precedented C2- A nd C3-selective functionalizations of benzyl amine derivatives, the present reaction can provide a new synthetic option for the synthesis of multi-substituted alicyclic compounds as well as aromatic compounds.

187. Acid-Catalyzed Cleavage of 1,4-Dimethyl-1,4-dihydronaphthalene 1,4-Endoperoxide. Reactivity of the Resulting Hydroxyperoxy Carbocation with Nucleophiles

In the presence of acids, 1,4-dimethyl-1,4-dihydronaphthalene 1,4-endoperoxie readily reacts with nucleophiles to produce methyl- and ring-substituted naphthalenes in high yields.The regioselectivity observed depends on the nucleophile.The key intermediate is shown to be the corresponding hydroperoxy carbocation which could be intercepted in certain cases prior to aromatization.The hydroperoxide also undergoes Hock-type cleavage and dimerization giving 2,3-dihydro-1-benzoxepins, 4-methyl-1-naphthol, and 1,2,5,6-tetraoxocane as by-products.

Functionalization of the Methyl Group of 1,4-Dimethyl-1,4-dihydronaphthalene-1,4-endoperoxide

The acid-catalysed cleavage of 1,4-dimethyl-1,4-dihydronaphthalene-1,4-endoperoxide gives the 4-hydroxy, methoxy, trifluoroacetoxy, formyloxy, bromo, and chloro methyl derivatives of 1-methylnaphthalene in yields of 36, 38, 52, 76, 77, and 100percent respectively when water, methanol, trifluoroacetic, formic, hydrobromic, or hydrochloric acids are used as reagents.