526221-22-7Relevant academic research and scientific papers
Stereospecific Construction of Chiral Quaternary α-Oxygenated Aldehydes from Chiral Secondary Alcohol Derivatives
Arasaki, Hideki,Iwata, Masashi,Nishimura, Daisuke,Itoh, Akichika,Masaki, Yukio
, p. 546 - 548 (2007/10/03)
Chiral tertiary dichloromethylcarbinol derivatives 2, prepared from protected chiral secondary alcohols 1, were converted stereospecifically into chiral quaternary α-oxygenated aldehyde derivatives 4 and 11 via intermediary α-chloroepoxides 3 under weakly
Stereospecific construction of chiral quaternary carbon compounds from chiral secondary alcohol derivatives
Masaki, Yukio,Arasaki, Hideki,Iwata, Masashi
, p. 4 - 5 (2007/10/03)
Chiral tertiary dichloromethylcarbinol derivatives, prepared by stereospecific α C-H insertion reaction of dichlorocarbene with protected chiral secondary alcohols, were converted into intermediary α-chloroepoxides which gave stereospecifically chiral qua
