52711-63-4Relevant academic research and scientific papers
Metal-free oxidative cross-dehydrogenative coupling of quinones with benzylic C(sp3)-H bonds
Dong, Yu,Yang, Jian,He, Shuai,Shi, Zhi-Chuan,Wang, Yu,Zhang, Xiao-Mei,Wang, Ji-Yu
, p. 27588 - 27592 (2019/09/12)
A metal-free cross-dehydrogenative coupling of quinones with toluene derivatives has been established. A series of quinones were subjected to reaction with toluene derivatives in the presence of di-tertbutyl peroxide (DTBP) for direct synthesis of benzylq
Enantioselective epoxidation of 2-substituted 1,4-naphthoquinones using gem-dihydroperoxides
Bunge, Alexander,Hamann, Hans-Jürgen,McCalmont, Eve,Liebscher, Jürgen
supporting information; experimental part, p. 4629 - 4632 (2009/10/26)
New gem-dihydroperoxides were successfully used for DBU-promoted enantioselective epoxidation of 2-substituted 1,4-naphthoquinones. The corresponding 1,4-naphthoquinone epoxides were obtained in yields up to 97% and ee's up to 82%.
A new synthetic route to substituted quinones by radical-mediated coupling of organotellurium compounds with quinones
Yamago, Shigeru,Hashidume, Masahiro,Yoshida, Jun-Ichi
, p. 6805 - 6813 (2007/10/03)
Carbon-centered radicals generated from the corresponding organotellurium compounds react with a variety of quinones under photo-thermal conditions to give the monoaddition product in moderate to excellent yield. The reaction can be used for the synthesis of polyprenyl quinoid natural products and C-glycosides.
