33440-68-5Relevant articles and documents
Metal-free oxidative cross-dehydrogenative coupling of quinones with benzylic C(sp3)-H bonds
Dong, Yu,Yang, Jian,He, Shuai,Shi, Zhi-Chuan,Wang, Yu,Zhang, Xiao-Mei,Wang, Ji-Yu
, p. 27588 - 27592 (2019/09/12)
A metal-free cross-dehydrogenative coupling of quinones with toluene derivatives has been established. A series of quinones were subjected to reaction with toluene derivatives in the presence of di-tertbutyl peroxide (DTBP) for direct synthesis of benzylq
The Application of 2-Benzyl-1,4-naphthoquinones as Pronucleophiles in Aminocatalytic Synthesis of Tricyclic Derivatives
Skrzyńska, Anna,Romaniszyn, Marta,Pomiklo, Dominika,Albrecht, Lukasz
, p. 5019 - 5026 (2018/05/17)
This study demonstrates an unprecedented reactivity of 2-substituted-1,4-naphthoquinones. By applying the principle of vinylogy, they have been employed as vinylogous pronucleophiles in the organocatalytic cascade reaction for the first time. This novel catalytic activation of 1,4-naphthoquinones enables access to carboannulated naphthalen-1(4H)-one derivatives of biological importance. The site-selectivity and stereoselectivity of a process proved possible to control by the proper choice of reaction conditions.
Enantioselective epoxidation of 2-substituted 1,4-naphthoquinones using gem-dihydroperoxides
Bunge, Alexander,Hamann, Hans-Jürgen,McCalmont, Eve,Liebscher, Jürgen
supporting information; experimental part, p. 4629 - 4632 (2009/10/26)
New gem-dihydroperoxides were successfully used for DBU-promoted enantioselective epoxidation of 2-substituted 1,4-naphthoquinones. The corresponding 1,4-naphthoquinone epoxides were obtained in yields up to 97% and ee's up to 82%.
