528604-26-4Relevant academic research and scientific papers
Confirmation of the structure of a glucono-1,4-lactone derivative obtained from silylation of glucono-1,5-lactone
Murphy, Paul V.,McDonnell, Ciaran,Haemig, Ludger,Paterson, Duncan E.,Taylor, Richard J. K.
, p. 79 - 85 (2003)
Silylation reactions of glucono-1,5-lactone can give the persilylated glucono-1,5-lactone or the persilylated 1,4-lactone depending on the reaction conditions employed. The structure of 2,3,5,6-tetra-O-(tert-butyldimethylsilyl)-D-glucono-1,4-lactone, obta
Effects of frozen conditions on stereoselectivity and velocity of O-glycosylation reactions
Ishiwata, Akihiro,Sakurai, Ayaka,Dürr, Katharina,Ito, Yukishige
experimental part, p. 3687 - 3695 (2010/08/03)
Rate acceleration of O-glycosylation had been observed in p-xylene under frozen conditions, when thioglycosides were activated by methyl trifluoromethane sulfonate. Curiously, significant perturbation of stereoselectivity was observed. Effects of various
