529510-50-7Relevant articles and documents
Stereoselective synthesis of C15-C24 and C25-C30 fragments of dolabelides
Desroy, Nicolas,Le Roux, Rémi,Phansavath, Phannarath,Chiummiento, Lucia,Bonini, Carlo,Genêt, Jean-Pierre
, p. 1763 - 1766 (2007/10/03)
The stereocontrolled synthesis of a C15-C24 fragment of dolabelides is reported. The C19 and C21 hydroxyl-bearing stereocenters were installed using ruthenium-mediated asymmetric hydrogenations of cyclic hemiketal 4 and β-keto ester 7. The C25-C30 portion