53006-28-3Relevant academic research and scientific papers
Asymmetric Hydrogenation of Racemic Allylic Alcohols via an Isomerization-Dynamic Kinetic Resolution Cascade
Guo, Xin,Niu, Saisai,Sun, Huaming,Tang, Weijun,Wang, Chao,Wang, Kun,Xiao, Jianliang,Xue, Dong
, (2022/02/05)
Prochiral racemic allylic alcohols are converted to enantioenriched chiral alcohols bearing adjacent stereocenters catalyzed by a diamine diphosphine Ru complex in the presence of tBuOK. The protocol features a broad substrate scope (56 examples) and high
Direct trifluoromethylthiolation of alcohols under mild reaction conditions: Conversion of R-OH into R-SCF3
Nikolaienko, Pavlo,Pluta, Roman,Rueping, Magnus
supporting information, p. 9867 - 9870 (2014/08/18)
A direct process for the trifluoromethylthiolation of allylic and benzylic alcohols under mild conditions has been developed. A wide range of free alcohols underwent nucleophilic substitution in the presence of stable CuSCF3 and BF3·Et2O to give the corresponding products in good to excellent yields.
