53017-44-0

Basic information

• Product Name: 5-benzyloxy-N_b-acetyl-L-tryptophan methyl ester
• CAS NO: 53017-44-0
• Molecular Weight: 366.417
• Mol File: 53017-44-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-benzyloxy-N_b-acetyl-L-tryptophan methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 5-benzyloxy-N_b-acetyl-L-tryptophan methyl ester(53017-44-0)
• EPA Substance Registry System: 5-benzyloxy-N_b-acetyl-L-tryptophan methyl ester(53017-44-0)

Safety Data

• Hazardous Substances Data: 53017-44-0(Hazardous Substances Data)

Upstream product

• 68-95-1 (S)-acetylproline 
• 147-85-3 L-proline 
• 2311-25-3 N-acetyl-L-proline methyl ester 
• 52068-30-1 4-benzyloxyphenylhydrazine hydrochloride 
• 154005-67-1 (S)-1-Acetyl-5-hydroxy-pyrrolidine-2-carboxylic acid methyl ester 

Downstream Products

• 56-69-9 5-hydroxy-L-tryptophan 
• 67010-10-0 N-acetyl-5-hydroxy-L-tryptophan 
• 53017-51-9 5-benzyloxy-N_b-acetyl-L-tryptophan 

Relevant articles and documents

Syntheses of Substituted L- and D-Tryptophans

Several 5-substituted nb-methoxycarbonyl-L- and -D-tryptophan derivatives were synthesized from proline by a new route involving electrochemical oxidation, as well as by the known procedures.Removal of the Nb-methoxycarbonyl group was accomplished by treatment with Me3SiI in refluxing chloroform, then alkaline hydrolysis of the methyl esters afforded 5-substituted L- and D-tryptophans with high optical purities.Keywords - L-tryptophan 5-substituted; D-tryptophan 5-substituted; anodic oxidation; N-methoxycarbonyl group deprotection; Fischer indole synthesis; iodotrimethylsilane