53084-05-2

Basic information

• Product Name: Ethanone, 2-(3,4-dimethoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)-
• CAS NO: 53084-05-2
• Molecular Formula: C17H18O5
• Molecular Weight: 302.327
• Mol File: 53084-05-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(3,4-dimethoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(3,4-dimethoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)-(53084-05-2)
• EPA Substance Registry System: Ethanone, 2-(3,4-dimethoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)-(53084-05-2)

Safety Data

• Hazardous Substances Data: 53084-05-2(Hazardous Substances Data)

Upstream product

• 24126-98-5 1-(2,4-dihydroxyphenyl)-2-(3,4-dimethoxyphenyl)ethan-1-one 
• 77-78-1 dimethyl sulfate 
• 93-40-3 (3,4-Dimethoxyphenyl)acetic acid 
• 108-46-3 recorcinol 
• 93-17-4 3,4-dimethoxyphenylacetonitrile 
• 74-88-4 methyl iodide 

Downstream Products

• 1621-61-0 cabreuvin 
• 857555-86-3 {2-[(3,4-dimethoxy-phenyl)-acetyl]-5-methoxy-phenoxy}-acetic acid 
• 56407-05-7 7,3',4'-Trimethoxyisoflavanone 
• 94104-28-6 3-Hydroxymethyl-7,3',4'-trimethoxyisoflavanone 
• 96682-27-8 2-Hydroxy-4-methoxyphenyl α-hydroxymethyl-3,4-dimethoxybenzyl ketone 
• 87538-46-3 1-(3,4-Dimethoxy-phenyl)-2-(2-hydroxy-4-methoxy-phenyl)-ethane-1,2-dione 
• 109469-76-3 2,4,3',4'-Tetramethoxy-benzil 
• 485-63-2 3',4',7-trihydroxyisoflavone 
• 492-24-0 3-(3,4-dihydroxy-phenyl)-7-methoxy-chromen-4-one 
• 873994-22-0 6-methoxy-3-veratryl-benzofuran 
• 111355-00-1 6-methoxy-3-veratryl-benzofuran-2-carbaldehyde 
• 854899-45-9 6-methoxy-3-veratryl-benzofuran-2-carbonitrile 
• 102159-37-5 1-(6-methoxy-3-veratryl-benzofuran-2-yl)-ethanone 
• 111329-58-9 6-methoxy-3-veratryl-benzofuran-2-carboxylic acid 

Relevant articles and documents

Enantioselective Synthesis of Isoflavanones and Pterocarpans through a RuII-Catalyzed ATH-DKR of Isoflavones

Noyori-Ikariya RuII complexes promoted the one-pot C=C/C=O bonds reduction of isoflavones using sodium formate as the hydrogen source through Asymmetric Transfer Hydrogenation-Dynamic Kinetic Resolution (ATH-DKR). Due to the neutral conditions employed, isoflavones with different substituents at the 2’-position of B-ring (H, OH, OMe and Br) were successfully reduced. Ten cis-3-phenylchroman-4-ols were selectively obtained (>20 : 1 dr) in good yields (up to 86 %) and excellent enantioselectivities (up to >99 : 1 er). The synthetic applications of these chiral compounds were also demonstrated. Enantioenriched isoflavanones were obtained under mild metal-free oxidation of the cis-3-phenylchroman-4-ols while pterocarpans were synthesized by two strategies: an acid-catalyzed cyclization and a novel approach based on a Pd-catalyzed C?O intramolecular cross-coupling reaction.