53097-25-9

Basic information

• Product Name: C₁₆H₁₄S
• Synonyms: C₁₆H₁₄S
• CAS NO: 53097-25-9
• Molecular Weight: 238.353
• Mol File: 53097-25-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₄S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₄S(53097-25-9)
• EPA Substance Registry System: C₁₆H₁₄S(53097-25-9)

Safety Data

• Hazardous Substances Data: 53097-25-9(Hazardous Substances Data)

Upstream product

• 104-55-2 3-phenyl-propenal 
• 79409-19-1 (phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane 
• 62813-20-1 trimethyl(phenylsulfanyltrimethylstannanylmethyl)silane 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Gem-Heterosubstituted (stannyl)methylsilanes as synthetic equivalents of functionalized α-stannyl(methyl) anions

α-Heterosubstituted silyl derivatives, such as phenylthio-, phenylseleno- and benzotriazolyl-stannyl silanes, react with aldehydes under tetra-n-butylammonium fluoride (TBAF) catalysis, leading to α-substituted-βhydroxy stannanes, able to behave as precursors of Z- and E-olefins, generated by deoxystannylation. This reactivity shows the capability of such heterosubstituted silanes to act as masked carbanions through a mild functionalization of the carbon-silicon bond.