53131-18-3Relevant articles and documents
The synthesis of 3-deoxy-4-O-methyl-D-arabino-2-heptulosonic acid and its behaviour in the Warren reaction.
Charon,Szabo
, p. 271 - 277 (1974)
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Expeditious synthesis of saponin P57, an appetite suppressant from Hoodia plants
Zhang, Jian,Shi, Hefang,Ma, Yuyong,Yu, Biao
supporting information; experimental part, p. 8679 - 8681 (2012/09/22)
Pregnane glycoside P57, the appetite suppressant component from Hoodia, was synthesized expeditiously, featuring preparation of the aglycone Hoodigogenin A from digoxin and assembly of the deoxytrisaccharide with glycosyl o-alkynylbenzoates as donors.
An Efficient Deoxysugar Synthesis using Bu4NBH4 via an SN2 Reduction
Sato, Ken-ichi,Hoshi, Toshio,Kajihara, Yasuhiro
, p. 1469 - 1472 (2007/10/02)
Deoxysugar derivatives were prepared from the corresponding triflate, tosylate, halogen, and epoxide derivatives.Employing the tetrabutylammonium tetrahydroborate reagent, the deoxygenation proceeds via an SN2 type displacement in good yield.