53190-01-5Relevant academic research and scientific papers
Bismuth Trichloride as a New Efficient Catalyst in the Aldol Reaction and the Michael Reaction
Wada, Makoto,Takeichi, Eiji,Matsumoto, Takashi
, p. 990 - 994 (2007/10/02)
In the presence of a catalytic amount of bismuth(III) trichloride (5 mol percent), silyl enol ethers react with aldehydes at room temperature in dichloromethane to give the corresponding aldols in good yields.Silyl enol ethers also have been found to reac
BISMUTH TRICHLORIDE AS A NEW EFFICIENT CATALYST IN THE ALDOL REACTION
Ohki, Hidenori,Wada, Makoto,Akiba, Kin-ya
, p. 4719 - 4722 (2007/10/02)
In the presence of a catalytic amount of bismuth trichloride (5 molpercent), silyl enol ethers react with aldehydes at room temperature to give the corresponding aldols in good yields.
SYNTHETIC CONTROL LEADING TO CHIRAL COMPOUNDS
Mukaiyama, Teruaki,Iwasawa, Nobuharu,Stevens, Rodney W.,Haga, Toru
, p. 1381 - 1390 (2007/10/02)
A highly diastereoselective cross aldol reaction is developed using divalent tin enolates formed from stannous trifluoromethanesulfonate and carbonyl compounds.The reaction is extended to a highly enantioselective cross aldol reaction employing chiral dia
STANNOUS TRIFLATE: A FACILE CROSS-ALDOL REACTION BETWEEN TWO KETONES VIA DIVALENT TIN ENOLATES
Stevens, Rodney W.,Iwasawa, Nobuharu,Mukaiyama, Teruaki
, p. 1459 - 1462 (2007/10/02)
Divalent tin enolates, formed from stannous triflate and ketones, react with a second ketone under mild conditions to afford the corresponding cross-aldol products in good to excellent yields.In the case of the cross-coupling with aromatic ketone, enhance
