5328-80-3

Basic information

• Product Name: 1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine
• Synonyms: 1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine;bis-(2-chlorobenzal)hydrazine;1,1'-(Azinobismethylidyne)bis(2-chlorobenzene);2-Chlorobenzalazine;2-Chlorobenzaldehyde (2-chlorophenylmethylene)hydrazone
• CAS NO: 5328-80-3
• Molecular Formula: C₁₄H₁₀Cl₂N₂
• Molecular Weight: 277.15
• Mol File: 5328-80-3.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 381.5°C at 760 mmHg
• Flash Point: 184.6°C
• Appearance: /
• Density: 1.21g/cm³
• Vapor Pressure: 1.11E-05mmHg at 25°C
• Refractive Index: 1.589
• CAS DataBase Reference: 1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine(5328-80-3)
• EPA Substance Registry System: 1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine(5328-80-3)

Safety Data

• Hazardous Substances Data: 5328-80-3(Hazardous Substances Data)

Usage

General Description

1-(2-chlorophenyl)-N-[(2-chlorophenyl)methylideneamino]methanimine, also known as Temic, is a synthetic amine compound that is used as a fungicide and pesticide. It acts as an inhibitor of protein synthesis in fungi, leading to their death. It is commonly used in agriculture to protect crops from fungal infections and is also used in the preservation of wood and timber. The compound is highly effective in controlling a wide range of fungal pathogens and is considered to be relatively safe for humans and the environment when used according to instructions. However, it is important to handle and apply this chemical with caution to avoid any potential harm.

InChI:InChI=1/C14H10Cl2N2/c15-13-7-3-1-5-11(13)9-17-18-10-12-6-2-4-8-14(12)16/h1-10H

Upstream product

• 873-32-5 2-Chlorobenzonitrile 
• 89-98-5 2-chloro-benzaldehyde 
• 52372-78-8 2-chlorobenzaldehyde hydrazone 
• 82988-74-7 (2-chlorophenyl)diazomethane 
• 124-73-2 1,2-dibromo-1,1,2,2-tetrafluoroethane 
• 76-13-1 1,1,2-Trichloro-1,2,2-trifluoroethane 
• 558-13-4 carbon tetrabromide 
• 354-58-5 1,1,1-Trichloro-2,2,2-trifluoroethane 

Downstream Products

• 25144-38-1 (E)-2,2'-dichlorostilbene 
• 792-39-2 bis(α,2-dichlorobenzylidene)hydrazine 
• 52372-78-8 2-chlorobenzaldehyde hydrazone 
• 74115-29-0 2-chloro-N'-(2-chloro-benzylidene)-benzohydrazonoyl chloride 
• 36951-39-0 2-chloro-benzaldehyde (4-oxo-thiazolidin-2-ylidene)-hydrazone 
• 36951-46-9 2-chloro-benzaldehyde [5-(2-chloro-benzylidene)-4-oxo-thiazolidin-2-ylidene]-hydrazone 
• 111474-67-0 2,2'-Dichlor-benzaldazin-monoxyd 
• 89-98-5 2-chloro-benzaldehyde 
• 78032-04-9 5-Chloro-1-(2-chloro-phenyl)-phthalazine 
• 108-90-7 chlorobenzene 
• 78032-08-3 5-chloro phthalazine 
• 108593-02-8 (2-Chlorphenyl)bis(methylthio)methan 
• 7647-01-0 hydrogenchloride 
• 873-32-5 2-Chlorobenzonitrile 

Relevant articles and documents

Ruthenium(ii)-catalysed 1,2-selective hydroboration of aldazines

Herein, an efficient and simple catalytic method for the selective and partial reduction of aldazines using ruthenium catalyst [Ru(p-cymene)Cl2]2 (1) has been accomplished. Under mild conditions, aldazines undergo the addition of pinacolborane in the presence of a ruthenium catalyst, which delivered N-boryl-N-benzyl hydrazone products. Notably, the reaction is highly selective, and results in exclusive mono-hydroboration and desymmetrization of symmetrical aldazines. Mechanistic studies indicate the involvement of in situ formed intermediate [{(η6-p-cymene)RuCl}2(μ-H-μ-Cl)] (1a) in this selective hydroboration.

An efficient synthesis of perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-dithiones catalyzed by TiO2-functionalized nano-Fe3O4 encapsulated-silica particles as a reusable magnetic nanocatalyst

Immobilization of a nano-TiO2 catalyst on the surface of a magnetic SiO2 support was performed through the reaction of a Fe3O4@SiO2 composite with Ti(OC4H9)4via a simple process. The Fe3O4@SiO2-TiO2 nanocomposite was characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), and a vibrating sample magnetometer (VSM). The Fe3O4@SiO2-TiO2 nanocomposite has been found to be an efficient catalyst for the synthesis of perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-dithiones from the condensation of various aldazines and potassium thiocyanate in acetonitrile solvent at room temperature. It has been found that the nanocatalyst was recycled for up to 6 cycles with minimal loss in catalytic activity. The purpose of this research was to provide an easy method for the synthesis of perhydrotriazolotriazole derivatives by a robust and magnetically recoverable catalyst.

An expeditious synthetic approach towards the synthesis of Bis-Schiff bases (aldazines) using ultrasound

Aldazines (Bis-Schiff bases) 1-24 were synthesized using aromatic aldehydes (heterocyclic and benzaldehydes) and hydrazine hydrate under reflux using conventional heating and/or via ultrasound irradiation using BiCl3 as catalyst. Ultrasonication conditions with cat. BiCl3 proved to be an effective, environmentally friendly synthetic procedure. This methodology is robust in the presence of electron donating and electron withdrawing groups affording desired products with high yields (>95%) in just a couple of minutes vs. hours using conventional heating.