53282-74-9Relevant academic research and scientific papers
A general method for synthesis of cis-dicarbonyl epoxides through DBU/LiBr-cocatalyzed cyclization of α,β-dicarbonyl peroxides
Zong, Zhenzhen,Bai, Xiaohui,Lu, Shenglin,Li, Zhiping
supporting information, p. 3827 - 3831 (2016/08/02)
A general method for synthesis of cis-dicarbonyl epoxides is developed. The highly diastereoselective cyclization of α,β-dicarbonyl peroxides is achieved by DBU/LiBr cocatalysis. The coordination of lithium ion with two carbonyl groups is proposed for the
Iron-catalyzed alkoxycarbonylation–peroxidation of alkenes with carbazates and T-Hydro
Zong, Zhenzhen,Lu, Shenglin,Wang, Wenxiao,Li, Zhiping
supporting information, p. 6719 - 6721 (2018/05/14)
Iron-catalyzed alkoxycarbonylation–peroxidation of alkenes with carbazates and T-Hydro was developed. A variety of β-ester peroxides were synthesized efficiently and selectively in a single step starting from readily available starting materials.
Enantiomerically Pure Building Blocks for Syntheses from Branched Malates
Aebi, Johannes D.,Sutter, Marius A.,Wasmuth, Daniel,Seebach, Dieter
, p. 2114 - 2126 (2007/10/02)
Isocitric acid lactone (13) and the chiral building blocks (2S,3R)-4-bromo-1,2-epoxy-3-methyl-butane (21), cis- and trans 2,3-epoxy-2-methylsuccinates (23, 24), and the singly protected (2R)-2-methyl-, -2-allyl- and -2-benzyl-1,3-propanediols (32a, b, c)
