53304-27-1Relevant academic research and scientific papers
Organozinc reagents in synthesis: The facile generation of 2-(trialkylsilyl)prop-2-enylzinc from 2-bromo-1-trimethylsilylprop-2-ene
Eshelby, James J.,Parsons, Philip J.,Crowley, Patrick J.
, p. 191 - 199 (1996)
A range of electrophiles react with 2-(trimethylsilyl)prop-2-enylzinc chloride, which is prepared by sequentially treating 2-bromo-1-trimethylsilylprop-2-ene with ButLi and then zinc chloride. The addition of transition metal catalysts can alter the reactivity of the organometallic compound from prop-2-enylation to prop-1-en-2-ylation.
Asymmetric hydrogenation of 1-silyl-1-substituted alkenes for preparation of optically active silanes
Ma, Dan-Dan,Gu, Peiming,Li, Rui
, p. 5666 - 5668 (2016)
Asymmetric hydrogenation of 1-silyl-1-substituted alkenes has been explored, producing eight optically active silanes with good to excellent enantioselectivity (66–99% ee) and yield (74–99%). The reaction was efficiently catalyzed by the cationic N,P-Ir c
