Journal of the Chemical Society. Perkin transactions I p. 191 - 199 (1996)
Update date:2022-07-31
Topics:
Eshelby, James J.
Parsons, Philip J.
Crowley, Patrick J.
A range of electrophiles react with 2-(trimethylsilyl)prop-2-enylzinc chloride, which is prepared by sequentially treating 2-bromo-1-trimethylsilylprop-2-ene with ButLi and then zinc chloride. The addition of transition metal catalysts can alter the reactivity of the organometallic compound from prop-2-enylation to prop-1-en-2-ylation.
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