5339-18-4

Usage

InChI:InChI=1/C10H13N/c1-4-9-7-5-6-8-10(9)11(2)3/h4-8H,1H2,2-3H3

Upstream product

• 579-72-6 2-(dimethylamino)benzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 698-00-0 2-bromo-N,N-dimethylaniline 
• 446-52-6 2-Fluorobenzaldehyde 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 50-00-0 formaldehyd 
• 3867-18-3 2-vinylaniline 
• 5339-85-5 2-aminophenethyl alcohol 
• 2554-06-5 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane 
• 14725-27-0 N,N-Dimethylindolinium iodide 
• 5339-27-5 2-(2-dimethylaminophenyl)ethyl alcohol 

Downstream Products

• 2058-74-4 1-methyl-1H-indole-2,3-dione 
• 1373497-84-7 (E)-1-methoxy-2-(3,3,3-trifluoroprop-1-en-1-yl)benzene 
• 875-30-9 1,3-dimethylindole 
• 39891-78-6 2,3-dihydro-1,3-dimethylindole 
• 6126-96-1 N,N-dimethyl ortho-ethylaniline 

Relevant academic research and scientific papers

Asymmetric Cycloisomerization of o-Alkenyl-N-Methylanilines to Indolines by Iridium-Catalyzed C(sp3)?H Addition to Carbon–Carbon Double Bonds

Highly enantioselective cycloisomerization of N-methylanilines, bearing o-alkenyl groups, into indolines is established. An iridium catalyst bearing a bidentate chiral diphosphine effectively promotes the intramolecular addition of the C(sp3)?H bond across a carbon–carbon double bond in a highly enantioselective fashion. The reaction gives indolines bearing a quaternary stereogenic carbon center at the 3-position. The reaction mechanism involves rate-determining oxidative addition of the N-methyl C?H bond, followed by intramolecular carboiridation and subsequent reductive elimination.

COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS

The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen

Chemo-, Regio-, and stereoselective trifluoromethylation of styrenes via visible light-driven single-electron transfer (SET) and triplet-triplet energy transfer (TTET) processes

A process for tunable and chemo-, regio-, and stereoselective photocatalytic trifluoromethylation of styrenes was developed. Thermodynamically stable E-trifluoromethylated alkenes were prepared using Tognis reagent in the presence of Ru(bpy)3Cl2·6H2O under visible light irradiation, whereas less thermodynamically stable Z-trifluoromethylated alkenes were obtained by employing Umemotos reagent and photocatalyst Ir(ppy)3.

Efficient cyclization of tertiary amines and alkenes promoted by KOt-Bu-DMF

Nitrogen heterocycles could be prepared in good yields via intramolecular cyclization of tertiary amines and alkenes promoted by KOt-Bu-DMF. This journal is The Royal Society of Chemistry 2013.

Vinylation of aryl bromides using an inexpensive vinylpolysiloxane

(Chemical Equation Presented) A mild and general method for the palladium-catalyzed vinylation of aryl bromides has been developed. The use of tetrabutylammonium fluoride (TBAF) as the activator and an inexpensive and nontoxic vinyl donor, 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (D4V, 1), allows for a general and high-yielding preparation of substituted styrenes.