53402-10-1

Basic information

• Product Name: (1R)-(-)-THIOCAMPHOR
• Synonyms: (1R)-(-)-THIOCAMPHOR;(1r)-(-)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-thione;(1R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2-thione;(1R)-(-)-Thiocamphor
• CAS NO: 53402-10-1
• Molecular Formula: C₁₀H₁₆S
• Molecular Weight: 168.3
• Product Categories: Bicyclic Monoterpenes;Biochemistry;Terpenes
• Mol File: 53402-10-1.mol
• Article Data: 20

Chemical Properties

• Melting Point: 136-138 °C(lit.)
• Boiling Point: 228-230 °C(lit.)
• Flash Point: 81.7 °C
• Appearance: /
• Density: 0.9691 (rough estimate)
• Vapor Pressure: 0.107mmHg at 25°C
• Refractive Index: 1.6500 (estimate)
• CAS DataBase Reference: (1R)-(-)-THIOCAMPHOR(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-(-)-THIOCAMPHOR(53402-10-1)
• EPA Substance Registry System: (1R)-(-)-THIOCAMPHOR(53402-10-1)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36
• RIDADR: UN 1325 4.1/PG 3
• WGK Germany: 3
• HazardClass: 4.1
• PackingGroup: III
• Hazardous Substances Data: 53402-10-1(Hazardous Substances Data)

Usage

Purification Methods

It forms red prisms from EtOH and sublimes under vacuum. It possesses a sulfurous odour and is volatile like camphor. [Sen J Indian Chem Soc 12 647 1935, Sen J Indian Chem Soc 18 76 1941.] The racemate crystallises from *C6H6 and has m 145o [138.6-139o, White & Bishop J Am Chem Soc 62 10 1940]. [Beilstein 7 III 419.]

InChI:InChI=1/C10H16S/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

Upstream product

• 76-22-2 Camphor 
• 72995-90-5 camphor pyrrolidinoenamine 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 464-49-3 (1R)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 126314-33-8 di-((1R)-bornyl)-disulfide 
• 770-53-6 bornan-2-one-hydrazone 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 5391-78-6 bornane-2-thiol 
• 31180-79-7 N-nitrocaphorimine 
• 59121-52-7 (1R)-(+)-thiocamphor S-oxyde 

Downstream Products

• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 2767-84-2 Camphorquinone 
• 76013-16-6 3-endo-(phenylseleninyl)camphor 
• 50404-35-8 thiocamphor S-oxide 
• 59056-08-5 1,7,7-Trimethyl-2-phenylmethanesulfonyl-bicyclo[2.2.1]hept-2-ene 
• 70136-66-2 thiobenzoic acid S-born-2-en-2-yl ester 
• 633308-89-1 (1R,2R,4R,4'S)-1,7,7-trimethyl-4'-phenylspiro[bicyclo[2.2.1]heptane-2,2'-[1,3]oxathiolane] 
• 633308-90-4 (1R,2S,4R,4'R)-1,7,7-trimethyl-4'-phenylspiro[bicyclo[2.2.1]heptane-2,2'-[1,3]oxathiolane] 
• 73886-28-9 2-(propargyloxyimino)-1,7,7-trimethyl-bicyclo[2,2,1]heptane 

Relevant articles and documents

Enantiospecific synthesis of substituted 1-norbornyl trifluoromethanethiosulfonates and 1-norbornanethiols

New homochiral 1-norbornylthiotriflates 6 and 7 and 1-norbornanethiols 8 and 9 are easily prepared starting from naturally occurring 2-norbornanones 1. The key step is the reaction of chiral 2-norbornanethiones 2 with Tf2O under mild conditions.

Formation of kinetically stabilized dithiiranes by treating thione S-oxides bearing a bulky substituent with Lawesson's reagent

Treatment of sterically crowded thione S-oxides derived from d-camphor with Lawesson's reagent afforded dithiiranes along with deoxygenation of the starting materials, and the mixtures were subjected to mCPBA oxidation to give the corresponding dithiirane S-oxides and thione S-oxides.

Dynamics of capsuleplex formed between octaacid and organic guest molecules - Photophysical techniques reveal the opening and closing of capsuleplex

This manuscript is concerned with the opening and closing of a capsuleplex made up of organic guest molecules and two cavitand molecules known as octaacid (OA). The capsuleplex is loosely held together in water through weak interactions. We have investiga

Expeditious microwave-assisted thionation with the system PSCl 3/H2O/Et3N under solvent-free condition

(Chemical Equation Presented) A novel thionation protocol for carbonyl compounds, with the system PSCl3/H2O/Et3N has been discovered. Clean, rapid, and efficient synthesis of a variety of thiocarbonyl compounds such as thioamides, thiolactams, thioketones, thioxanthones, and thioacridone can be achieved through this simple and convenient method under solventless condition with microwave irradiation.