31180-79-7Relevant academic research and scientific papers
AMINATION AND HYDROXYLATION OF ARYLMETAL COMPOUNDS
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Paragraph 0098; 0100; 0103; 0104, (2018/03/25)
In one aspect, the present disclosure provides methods of preparing a primary or secondary amine and hydroxylated aromatic compounds. In some embodiments, the aromatic compound may be unsubstituted, substituted, or contain one or more heteroatoms within the rings of the aromatic compound. The methods described herein may be carried out without the need for transition metal catalysts or harsh reaction conditions.
Urea activation of nitrimines: A mild, metal-free approach to sterically hindered enamines
Nickerson, David M.,Angeles, Veronica V.,Mattson, Anita E.
supporting information, p. 5000 - 5003 (2013/10/22)
Nitrimines have been identified as impressive starting points for the syntheses of otherwise inaccessible, sterically encumbered enamines. The activation of nitrimines with urea catalysts for reaction with a variety of amines enables the formation of high
ON THE FORMATION AND NITROGEN NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME NITRIMINES ('PERNITROSO-KETONES'), AND THE MECHANISM OF OXIME CLEAVAGE BY NITROUS ACID
Adamopoulos, Spiros,Boulton, A. J.,Tadayoni, Rahim,Webb, Graham A.
, p. 2073 - 2078 (2007/10/02)
The formation of nitrimines, by the action of nitrous acid in oximes, is shown to proceed without scrambling of the nitrogen atoms, the oxime nitrogen forming the imine, and the nitrous acid generating the nitro group.Colorued intermediates in the reaction are proposed to be nitrosimines.The mechanism of nitrosative deoximation, and the nitrogen NMR spectra of nitrimines, are reported and discussed.
