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(2E)-1,7,7-trimethyl-N-nitrobicyclo[2.2.1]heptan-2-imine is a nitroalkene compound characterized by a bicyclo[2.2.1]heptane skeleton, featuring a nitrogen atom, a nitro group, and a double bond at the 2-position. This yellow solid at room temperature is a versatile building block in organic synthesis, particularly for the production of pharmaceuticals, agrochemicals, and other fine chemicals due to its unique structure and reactivity.

31180-79-7

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31180-79-7 Usage

Uses

Used in Pharmaceutical Industry:
(2E)-1,7,7-trimethyl-N-nitrobicyclo[2.2.1]heptan-2-imine serves as a key intermediate in the synthesis of various pharmaceuticals, leveraging its reactive functional groups to form a wide range of bioactive compounds.
Used in Agrochemical Industry:
(2E)-1,7,7-trimethyl-N-nitrobicyclo[2.2.1]heptan-2-imine is utilized as a precursor in the development of agrochemicals, contributing to the creation of effective products for agricultural applications.
Used in Organic Chemistry Research:
(2E)-1,7,7-trimethyl-N-nitrobicyclo[2.2.1]heptan-2-imine is employed as a building block in organic chemistry for the synthesis of complex organic compounds, exploring its potential in forming various derivatives with different functional groups.

Check Digit Verification of cas no

The CAS Registry Mumber 31180-79-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,1,8 and 0 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 31180-79:
(7*3)+(6*1)+(5*1)+(4*8)+(3*0)+(2*7)+(1*9)=87
87 % 10 = 7
So 31180-79-7 is a valid CAS Registry Number.

31180-79-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (NE)-N-(4,7,7-trimethyl-3-bicyclo[2.2.1]heptanylidene)nitramide

1.2 Other means of identification

Product number -
Other names N-nitrocaphorimine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:31180-79-7 SDS

31180-79-7Relevant academic research and scientific papers

AMINATION AND HYDROXYLATION OF ARYLMETAL COMPOUNDS

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Paragraph 0098; 0100; 0103; 0104, (2018/03/25)

In one aspect, the present disclosure provides methods of preparing a primary or secondary amine and hydroxylated aromatic compounds. In some embodiments, the aromatic compound may be unsubstituted, substituted, or contain one or more heteroatoms within the rings of the aromatic compound. The methods described herein may be carried out without the need for transition metal catalysts or harsh reaction conditions.

Urea activation of nitrimines: A mild, metal-free approach to sterically hindered enamines

Nickerson, David M.,Angeles, Veronica V.,Mattson, Anita E.

supporting information, p. 5000 - 5003 (2013/10/22)

Nitrimines have been identified as impressive starting points for the syntheses of otherwise inaccessible, sterically encumbered enamines. The activation of nitrimines with urea catalysts for reaction with a variety of amines enables the formation of high

ON THE FORMATION AND NITROGEN NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME NITRIMINES ('PERNITROSO-KETONES'), AND THE MECHANISM OF OXIME CLEAVAGE BY NITROUS ACID

Adamopoulos, Spiros,Boulton, A. J.,Tadayoni, Rahim,Webb, Graham A.

, p. 2073 - 2078 (2007/10/02)

The formation of nitrimines, by the action of nitrous acid in oximes, is shown to proceed without scrambling of the nitrogen atoms, the oxime nitrogen forming the imine, and the nitrous acid generating the nitro group.Colorued intermediates in the reaction are proposed to be nitrosimines.The mechanism of nitrosative deoximation, and the nitrogen NMR spectra of nitrimines, are reported and discussed.

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